Advances in Physical Organic Chemistry APLAdvances in Physical Organic Chemistry APL |
Common terms and phrases
acid AGST alcohol alkyl amine amphiphiles anionic aromatic carbenes atoms base bimolecular binding Bunton calculated carbene catalysis cationic micelles Chem chemical compounds concentration counterions CTABr cyclisation cyclisation reactions cycloalkanes cyclohexane cyclopropane defined electron EM-values EM’s end-groups energy entropy equilibrium constant ether experimental Fendler first first-order formation functional micelles Galli head groups Hibbert hydrogen bond hydrolysis hydrophilic hydrophobic hydroxide ion Illuminati interactions intermediate intramolecular intramolecular hydrogen bond ionic irradiation isotope effect kinetic Mandolini Me2SO mechanism methylene micellar effects micellar pseudophase micellar surface micelles microemulsions molecular molecule monoanions nucleophilic observed orbital oxygen p-nitrophenyl Phys profile proton removal proton transfer proton-transfer rate coefficient rate constants reactants reactivity ring closure ring-size Romsted Scheme second-order rate constants significant similar singlet singlet carbene solvent specific Stern layer structure substituents substrate surfactant Table tautomers temperature tion transition triplet carbene vesicles Winnik