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Chapter 2 The Decomposition of Halogen Compounds
Chapter 3 The Decomposition of Aldehydes and Ketones
Chapter 4 The Unimolecular Decomposition and Isomerization of Oxygenated Organic Compounds Other than Aldehydes and Ketones
Chapter 5 Unimolecular Homogeneous Decompositions and Isomerizations of Nitrogen Compounds
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acetaldehyde acetate acetone acetyl acetylene acid activation energy activation parameters aldehyde alkyl allyl Arrhenius parameters Ausloos azide benzene biacetyl biradical Blacet bond bromide C2Hs carbon chain Chem chloride compounds cyclobutane cyclohexane cyclopentanone cyclopropane decarboxylation decompose decrease dissociation E. W. R. STEACIE effect electron elimination elimination reaction esters ether ethylene excited experimental Faraday Soc first-order formation formed free radical gas phase halogen hydrocarbons hydrogen atom increase inhibited initial intermediate investigations iodide iodine isobutene isomerization isotope kcal.mole ketones kinetics Laidler MACColl mechanism methane methyl radicals molecular molecule nitrogen Noyes observed occur olefin peresters peroxide photochemical photolysis Phys pressure primary process primary step Proc propene pyrolysis quantum yields radiolysis rate coefficient ratio reactant reaction rearrangement recombination reported sect singlet solvent studies substitution suggested t-butyl temperature thermal decomposition thermolysis tion toluene torr Trans transition triplet unimolecular vinyl wavelength