Fundamentals and Applications of Organic Electrochemistry: Synthesis, Materials, DevicesThis textbook is an accessible overview of the broad field of organic electrochemistry, covering the fundamentals and applications of contemporary organic electrochemistry. The book begins with an introduction to the fundamental aspects of electrode electron transfer and methods for the electrochemical measurement of organic molecules. It then goes on to discuss organic electrosynthesis of molecules and macromolecules, including detailed experimental information for the electrochemical synthesis of organic compounds and conducting polymers. Later chapters highlight new methodology for organic electrochemical synthesis, for example electrolysis in ionic liquids, the application to organic electronic devices such as solar cells and LEDs, and examples of commercialized organic electrode processes. Appendices present useful supplementary information including experimental examples of organic electrosynthesis, and tables of physical data (redox potentials of various organic solvents and organic compounds and physical properties of various organic solvents). |
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Contents
Contents | 129 |
Related Fields of Organic Electrochemistry | 187 |
Examples of Organic Electrosynthesis | 209 |
Index | 223 |
About the Authors | vii |
Methods for Organic Electrosynthesis | 33 |
Organic Electrosynthesis | 83 |
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Common terms and phrases
acid Ag/Ag+ alcohol alkyl anion anodic oxidation Applications of Organic aqueous aromatic BDD electrodes carbon carbonyl catalyst cathode cathodic reduction Chem chemical reactions chemistry chemoselective compounds conducting polymers current density current efficiency divided cell electrochemical electrochemical fluorination electrochemical reaction electroconductivity electrode material electrode potential electrode surface electrogenerated electrolytic electrolytic reactions electrolytic solution electron transfer Fermi-level fluorination Fundamentals and Applications halide heteroatom hydrogen hydrophobic Inagi ionic liquids John Wiley Kolbe electrolysis layer Lett Mahito Atobe mediator metal methanol method Methodology of Organic monomer Nonaka nucleophiles one-electron Organic Electrochemical Synthesis Organic Electrochemistry Organic Electrochemistry Figure Organic Electrode Reactions Organic Electrosynthesis organic solvents organic synthesis overpotential oxidation potential oxygen paired electrosynthesis phthalide polarity polymerization polypyrrole potential window proton reagents redox reference electrode regioselectivity shown in Eq shown in Figure solvents supercritical supercritical fluids supporting electrolyte Toshio Fuchigami ultrasonication viscosity voltammetry voltammograms Wiley & Sons