Acetic Acid and its DerivativesVictor H. Agreda Striking a balance between basic chemistry and chemical engineering, this up-to-date reference discusses important aspects of acetic acid and its major derivatives, including chemistry, methods of preparation and manufacture, and synthesis, as well as current and emerging downstream technologies.;The book provides comprehensive physical property da |
Contents
Chapter 1 Bioderived Acetic Acid | 3 |
Chapter 2 Ethylene and AcetyleneBased Processes | 15 |
Chapter 3 Manufacture via Hydrocarbon Oxidation | 27 |
Chapter 4 Manufacture via Methanol Carbonylation | 35 |
Chapter 5 Other Synthesis GasBased AceticAcid Processes | 53 |
Chapter 6 Production Economics | 61 |
I I Thermophysical Properties of AceticAcid and Its Aqueous Solutions | 71 |
Chapter 7 Acetic Acid | 73 |
Chapter 10 Ketene | 161 |
Chapter 11 Di ketene and Acetoacetates | 173 |
Chapter 12 Vinyl Acetate | 225 |
Chapter 13 Cellulose Acetate | 241 |
Chapter 14 Alcohol Acetates | 257 |
Chapter 15 Halogenated Derivatives | 285 |
Chapter 16 Nitrogen Derivatives | 305 |
Chapter 17 Specialty Chemicals | 323 |
Chapter 8 Aqueous Solutions | 101 |
I I I Selected Acetic Acid Derivatives | 143 |
Chapter 9 Acetic Anhydride | 145 |
Acrylics and OtherCarboxylic Acids | 345 |
Chapter 19 Key Properties and Hazards | 361 |
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Common terms and phrases
Abstr acetaldehyde Acetamide acetate esters acetic acid acetic anhydride acetoacetamides acetoacetate acetoacetylated acetyl chloride acid derivatives acrylic acid addition alcohol amines applications aqueous azeotrope by-product carbon monoxide carbonylation Catal catalyst cellulose acetate Chem chemistry chloroacetic acid CO₂ commercial concentration container Data from Ref density diketene dimer distillation Eastman Chemical Company equation equilibrium esterification esters estimated by means ethylene ethylidene diacetate European Patent Appl Experimental exposure limits flammable formation halogenated hazard heat capacity Hoechst hydrogen hydrolysis industrial Inhalation intermediate irritation ketene ketone Khim Kingsport liquid phase material means of Eq metal methanol method methyl acetate methyl iodide Molecular monomer olefins oxidation oxygen palladium polymerization polymers preparation pressure properties reaction reactive reactor reacts resins rhodium salt SECTION skin solubility solvent spill sulfuric acid Table temperature Tennessee thermal conductivity U.S. Patent vapor vinyl acetate viscosity water spray Water/Acetic Acid Mixtures yield