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Chemistry of the System H20C02CaC03
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aperture aquifer average bedding plane boundary conditions boundary layer Buhmann and Dreybrodt C02 conversion C02 pressure calcite dissolution calcite surface calcium calculated carbonate cave development cave passages channels chemical kinetics closed system cm year-1 curves dependence determined diameter diffusion boundary layer dissolution rates dissolved distance elementary reactions equilibrium Ewers experiments factor Figure first-order fissures flow velocity flux fracture function given groundwater HC0J hydraulic gradient hydraulic head hydrodynamic increasing initial input ionic joints karst systems karst water karstification laminar flow limestone mass transport mmol molecular diffusion obtained open system output particles pCo2 pcoj penetration lengths permeability phreatic phreatic zone Plummer porous medium precipitation rates rate constant rate equation rate laws region rock saturation shown in Fig shows solution species speleothems stalagmite supersaturated temperature thickness tion tubes turbulent flow vadose vadose zone values water table writeln Drucker zone