Transition Metal Mediated Organic Synthesis |
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Contents
Asymmetric Hydrogenations with Rhodium Chiral Phosphine Catalysts | 16 |
Stereospecific and Regioselective Hydrogenation of the Tricyclo4 2 2 025 | 23 |
Asymmetric Synthesis via PolymerAttached Optically Active Catalysts By | 35 |
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Common terms and phrases
1-pentene acid active added addition alcohol allyl amine amounts appears asymmetric atom base benzene bond carbon carbonyl carried catalyst Chem Chemical chemistry chiral cobalt complex compounds concentration containing conversion coordination coupling derivatives determined diene DIOP double effect electron Equation example experiments FIGURE formation formed gave give homogeneous hydride hydroformylation hydrogenation important increases indicated initial intermediate involved isomerization isoprene leading Lett ligand mechanism metal metal carbonyl methyl mixture mmoles mole norbornadiene observed obtained occur olefin optical organic Organomet oxidation palladium phase phosphine polymer possible precursor prepared presence pressure proposed radical ratio reaction reduction Reference reported rhodium SCHEME selectivity shown shows similar solution solvent species spectra spectrum step stereoselectivity steric structure studies substitution suggests synthesis TABLE temperature Tetrahedron thermal tion trans trans/cis transition metal various yield
Bibliographic information
| Title | Transition Metal Mediated Organic Synthesis Volume 333 of Annals Series Volume 333 of Annals of the New York Academy of Sciences, New York Academy of Sciences, ISSN 0077-8923 Annals vol.333 Volume 333 of New York Academy of Sciences: Annals of the |
| Editors | Donald Warren Slocum, O. R. Hughes |
| Contributor | New York Academy of Sciences |
| Publisher | New York Academy of Sciences, 1980 |
| Original from | the University of Michigan |
| Digitized | Feb 17, 2010 |
| ISBN | 0897660390, 9780897660396 |
| Length | 301 pages |
| Export Citation | BiBTeX EndNote RefMan |