A Solution Model for Gas Chromatographic Studies |
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Contents
General Theory | 12 |
Literature Review | 40 |
New Expressions for Thermodynamic Functions | 76 |
9 other sections not shown
Common terms and phrases
activity coefficient Appendix applied assumed benzene calculated carbon cell energy Chapter chemical combinatorial compounds configurational considered constant contact energy differences contains contribution coordination number core volume corresponding defined degree of freedom density dependence derived discussed effect equation ether excess enthalpy excess entropy excess free energy excess properties excess volume experimental expression external degree Figure Flory Flory-Huggins follow forces gas chromatography gives heat hydroxyl group ideal important indicates infinite dilution interaction internal liquid literature measured method mixing mixture molar excess free molar volume mole fraction molecules n-alkanes n-Octane obtained parameters Partial molar excess partition function phase polymer positive predict pressure properties pure pure component quantity reduced volume reference regular relation represents rule separation shown similar simple solution solution theory solvent structure suggested Table temperature term tion values vapor volume change