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INTRODUCTION AND SUMMARY
INSTRUMENTS AND METHODS
DIPOLE MOMENT OF CHARGETRANSFER COMPLEXES
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1,2-benzanthracene 6Erep absorption according to equ acetonitrile amyl alcohol anthracene anthracene-DEA aromatic hydrocarbons AVexP band Benzonitrile biphenyl calculated chapter charge-transfer complex Chem CM CM CM CN CN complex emission intensity complex formation concentration decrease dielectric constant diethylaniline different solvents diffusion coefficients dipole moments electron affinity electron donor equations excimers excited charge-transfer complex excited complex fluor fluorescence quenching fluorescence spectra Franck-Condon ground free enthalpy change hvcmax increasing solvent polarity interaction ionization potential kcal/mole kcTo Leonhardt lifetime Mataga Maximum emission frequencies methylcyclohexane n-hexane N,N-diethylaniline naphthalene nonpolar solvents nsec obtained perylene Phys plex plotted polar solvents pressure dependence primarily excited pure charge-transfer pyrene quantum yield quenching reaction rate constants reactants solvation solvation energy solvent dependence solvent molecules solvent-shared ion pair temperature dependence tetracene thesis toluene triethylamine wave function Weller