An Introduction to Statistical Thermodynamics |
Contents
STATISTICALMECHANICAL ENSEMBLES | 1 |
FURTHER DISCUSSION OF ENSEMBLES | 33 |
GENERAL RELATIONS FOR INDEPEndent DistingUISHABLE | 59 |
Copyright | |
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activity applicable approximation assumed average becomes calculate Chapter charge chemical classical coefficient component condition consider constant contribution corresponding crystal curve defined density depends Derive dilute discussion distribution effects electronic energy ensemble entropy equation equilibrium exact example expansion experimental expression fact fixed force given gives Hence ideal independent integral interaction intermolecular ions lattice leads limit liquid mean mechanics method molecular molecules obtain pair particles partition function phase polymer positive possible potential potential energy present pressure probability Problem properties pure quantum quantum mechanics radial distribution function referred relation result rotation Section Show single solute molecules solution solvent statistics surface symmetry temperature term theory thermodynamic tion unit variables vibrational virial volume zero