An Introduction to Statistical Thermodynamics |
Contents
STATISTICALMECHANICAL ENSEMBLES | 1 |
GENERAL RELATIONS FOR INDEPENDENT DISTINGUISHABLE | 59 |
IDEAL MONATOMIC | 74 |
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adsorbed adsorbed molecules adsorption approximation assumed atoms average binary Bose-Einstein Bragg-Williams calculate canonical ensemble Chapter Chem chemical potential component configuration consider constant coordinates corresponding crystal curve deduce degrees of freedom density Derive dilute discussion distribution electronic energy levels entropy equation equilibrium example experimental Fermi-Dirac free energy frequency gases grand partition function heat capacity Hence ideal gas independent integral interaction intermolecular forces ions isothermal kT ln lattice gas limit linear liquid microcanonical ensemble molecular monatomic N₁ nearest-neighbor notation number of molecules one-component one-dimensional pair particles phase Phys polyatomic polyelectrolyte polymer polymer molecules potential energy pressure probability Problem quantum quantum-mechanical radial distribution function reaction rotation second virial coefficient Section solute molecules solvent statistical mechanics statistical-mechanical subsystems surface symmetry temperature term theory thermodynamic functions tion variables vibrational virial coefficient volume zero