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Statistical Mechanics and Thermodynamics
The Ideal Gas at Equilibrium
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additivity applied approximation argon assumed assumption average calculated Chap charge Chem classical collision compared Comparison components computed configuration consider constant contributions coordinates correlation corresponding critical defined density depends derived determined direction discussed distance distribution function effects empirical energy ensemble equation evaluated example experiment experimental expression factor FIGURE fluid follows forces gases given gives hard hard-sphere Illustration independent integral interaction involved Kihara Lennard-Jones limit liquid mass mean measurements mechanics method mixture molecular molecules obtained pair potential parameters particles phase Phys position possible predict pressure probability properties quantum quantum mechanics radial distribution function range reduced respectively separation shown shows simple solution spheres statistical Table temperature theory thermodynamic transport unit values virial coefficients viscosity volume wave zero