The Photodissociation of Nitromethane Using Energy-selective Electron Impact Ionization and Time-of-flight Mass Spectrometry, Volume 2
University of Wisconsin--Madison, 1991 - 882 pages
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17-eV mass spectrum 300-V ion extraction 61 peaks absolute quantum yield absorption cross section absorption spectrum amount argon background backing pressure bond dissociation energy CH3 from nitromethane CH3+ signal CH3NO+ Chapter Chem CHNO cluster beam cluster dissociation clusters and monomers detect dimers dissociation of nitromethane dissociation partner dissociative ionization electron beam electron energy electron gun pulse electron-impact Equation error bars Figure fitting parameters function of wavelength gun pulse length helium instrument function interaction region laser power laser shots laser-induced fluorescence mass spectrometer mass-focusing measurements methyl iodide methyl ion signal monomer and cluster monomer beam monomer dissociation nitromethane and methyl nitromethane clusters nitromethane monomers NO2+ nsec peak shapes photodissociation of nitromethane photodissociation signal Phys primary photofragments raw signal recoil anisotropy recoil energy recoil momentum relative quantum yield room temp cell ScH3+ signal levels spectra Table time-of-flight trimers values versus dissociation wavelength xenon yield for CH3