The Organic Chemistry of Phosphorus, Volume 1 |
Contents
References | 11 |
Biphilicity of phosphorus compounds | 19 |
Nucleophilic attack on phosphorus | 25 |
Copyright | |
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Abstr acid addition compound adduct Akad alcohol aldehydes alkoxide alkyl halide amines Angew Arbusov reaction aromatic attack on halogen attack on oxygen betaine biphilic carbon atom carbonyl compounds carbonyl group catalysis Chem chloride CHPh D. B. DENNEY dialkyl diethyl disulphides Dokl double bond electron electrophilic enol phosphate epoxide esters ethyl example favoured formation formed free radical give H₂O halogen HORNER hydrolysis initial attack intermediate involved Khim leaving group lone pair mechanism molecule Nauk SSSR nitrogen nucleophilic attack nucleophilic displacement observed Obshch occurs olefin oxygen oxygen atom pentacovalent Perkow reaction peroxide Ph Ph Ph₂P Ph3P phenyl phos phosphine oxide phosphonium salts phosphorane phosphorus atom phosphorus compounds phosphoryl PPh3 presence presumably proton RAMIREZ react reactivity readily rearrangement solvent stabilised stable strongly structure substituents suggested sulphur tertiary phosphines tetrahedral Tetrahedron Letters transition trialkyl phosphites triethyl phosphite triphenyl triphenylphosphine trivalent phosphorus Wittig Wittig reaction
