## Part I. Statistical thermodynamics of small molecules and their mixtures: Part II. Effect of intramolecular interaction on macromolecular configuration in dilute solution |

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acetone agreement approximation assumed assumption benzene Berry binary mixtures cal mole calculated and observed calculated excess volume calculated from Eq calculated intrinsic viscosities carbon disulfide-acetone carbon tetrachloride cc mole cell model cell theory Chapter component configuration constant curve cyclohexane decalin determined deviation dipolar dipole Domb equation evaluated excess enthalpy excluded volume expansion factor experimental excess Fixman Flory free energy Hence interactions intermolecular intrinsic viscosity intrinsic viscosity data lattice least squares low molecular weight mean-square radius measured mercury nitromethane and acetonitrile non-polar molecule non-random mixing numerical integration observed excess entropies observed excess volumes obtained osmotic pressure partition function PIB-benzene polar polar molecule polarizability polymer polystyrene proportional pure liquid quantity radius of gyration random mixing ratio reduced volume shear rate shown solvent specific viscosity Table Theorem of Corresponding theory and experiment thermal expansion coefficient thermal pressure coefficient thermodynamic tion unperturbed volume exclusion yields zero