John Wiley & Sons, Mar 26, 2009 - Science - 525 pages
The chemistry of superacids has developed in the last two decades into a field of growing interest and importance. Now available in a new expanded second edition, this definitive work on superacids offers a comprehensive review of superacids and discusses the development of new superacid systems and applications of superacids in the promotion of unusual reactions. Covering Bronsted and Leurs superacids, solid superacids, carbocations, heterocations, and catalyzed reactions, this timely volume is invaluable to professionals, faculty, and graduate students in organic, inorganic, and physical chemistry.
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13C NMR 1H NMR alcohols alkanes alkyl Angew aromatic atoms benzene bond distances bond lengths CĄC CĄH bond calculated carbenium ions carbon carbonyl Catal catalyst cation CF3SO3H Chem chemical shifts Chemistry Chim chloride compounds corresponding cyclopropyl delocalization deshielded dication diprotonated electron electrophilic energy Engl ether fluorine formation G. A. Olah G. K. S. Prakash H H H HF–SbF5 HSO3F hydride hydrocarbons hydrogen indicate Inorg intermediate ionization isobutane isomerization isomers Jacquesy K. O. Christe kcal kcal molĄ1 Lewis acid Magic Acid methane methyl Minkwitz Nafion Nafion-H NMR chemical shifts NMR spectroscopy NMR spectrum observed oxidation Ph Ph phenyl Phys prepared protonated R. J. Gillespie Rasul react reaction reactive rearrangement resonance ring salts SbF5 Scheme Schleyer showed solution species spectra stable studies sulfuric sulfuric acid superacid symmetry synthesis tert-Bu tertiary Tetrahedron Lett toluene triflic acid X-ray yield