Biomineralization I: Crystallization and Self-Organization Process

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Kensuke Naka
Springer Science & Business Media, 2007 - Science - 199 pages
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In nature, biological organisms produce mineralized tissues such as bone, teeth, diatoms, and shells. Biomineralization is the sophisticated process of production of these inorganic minerals by living organisms. Construction of organic–inorganic hybrid materials with controlled mineralization analogous to those produced by nature has recently received much attention because it can aid in understanding the mechanisms of the biomineralization process and development of biomimetic materials processing. The biomineralization ? processes use aqueous solutions at temperatures below 100 C and no toxic intermediates are produced in these systems. From a serious global en- ronmental problem point of view, the development of processes inspired by biomineralization would offer valuable insights into material science and en- neering to reduce energy consumption and environmental impact. One of the most challenging scienti?c problems is to gain greater insight into the mol- ular interactions occurring at the interface between the inorganic mineral and the macromolecular organic matrix. Model systems are often regarded as a straight-forward experimental approach toward biomimetic crystallization. Hierarchical architectures consisting of small building blocks of inorganic cr- tals are often found in biominerals. Studies of nanocrystal self-organization in solution systems would also be helpful for understanding biomineralization. In these volumes, we focus on construction of organic–inorganic hybrid - terials with controlled mineralization inspired by natural biomineralization. In the?rst volume, thereader will ?nd contributionsproviding abasic scopeof the mineralization process in aqueous solution.
 

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Contents

Suitable Models of MineralMatrix Interactions in Biomineralization?
16
Rüdiger Kniep uPaulSimon
40
SelfOrganized Formation of Hierarchical Structures
45
1Introduction
74
Overall Characterization of the Fractal Composite Aggregates
89
The Virgin Composite Seed Fractal Series
100
IonImpregnation PreStructuring of the GelatineGel
107
Electrical Fields Fractal Series
115
First Applications
121
InorganicOrganic Interfacial Interactions
128
Detoxification Biominerals
154
Author IndexVolumes251271
187
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