Chemical Kinetics and DynamicsThis book offers a presentation of the macroscopic view of empirical kinetics and the microscopic molecular viewpoint of chemical dynamics. |
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1st kind A₁ absorption activation energy analytic approximation atoms Bessel function bimolecular calculated chapter Chem Chemical Kinetics chemical reaction cm³ collision complex reactions consider cont cross section d[A₂ derived determined differential equations diode laser dissociation eigenvalues electronic equilibrium error Euler method experimental first-order force constant frequency function of 1st given H₂ H₂O initial condition integration ions k₁ k₁[A₁ k₂ kinetic equations kJ/mole Laplace transform linear matrix measurements molecular molecules number of molecules obtain one-step methods p₁ p²(p parameters partition function Phys plot potential energy surface problem rate coefficient rate constant rate equations rate expression rate law reac reactant reaction coordinate reaction path reactive Runge-Kutta method second-order shown in Figure solution solve species steady-state step stochastic TABLE technique temperature tion transition state theory variable vibrational Vp² York zero Σω