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absorption acid acrolein acrylamide alkyl amorphous atoms average molecular weight benzene butadiene calculated carbon catalyst Chem Chemical chloride column compounds concentration copolymer copolymerization crosslinking crystal crystalline curve decomposition decrease degradation density determined distribution dose rate effect electron energy equation ethylene experimental fibers formation fraction free radical groups heat hydrocarbon hydrogen increase indicate infrared initial intrinsic viscosity irradiation isoprene isotactic kinetic linear measurements mechanism melting point methacrylate methanol method methyl mixture mole molecules monomer nitrogen observed obtained oxidation oxygen peak peroxide phase phenolic Phys plot poly polyacrolein polycarbonate polyethylene polymer Polymer Sci polymerization polypropylene polystyrene present pressure propagation propylene pyrolysis radiation rate constant ratio reaction resin sample scission shown in Figure shows solid soluble solution solvent spectra spherulite stereoregular structure styrene sulfonic acid sulfur surface syndiotactic Table termination tetrahydrofuran thermal tion trioxane values vinyl X-ray yield