Organotransition Metal Chemistry: From Bonding to Catalysis

Front Cover
University Science Books, Feb 10, 2010 - Science - 1100 pages
Based on Collman et al.'s best-selling classic text, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.

From inside the book

 

Contents

Structure and Bonding
10
References and Notes
26
Dative Ligands
27
Copyright

45 other sections not shown

Common terms and phrases

18-electron acid aldehydes alkane alkenes alkoxide alkyl alkyl complexes alkyl group alkynes allyl amido amines ancillary ligands Angew anionic arene aryl halides B-hydrogen elimination Bergman binding C-H bond carbene complexes carbon carbonyl catalysts containing catalyzed cationic Chapter Chem chemistry chiral complexes containing compounds coordination coupling dienes dihydrogen dissociation electron electrophilic enantioselective esters ethylene example Figure H₂ Hartwig hydride hydroamination hydroformylation hydrogenation hydrosilylation imido Inorg intermediate intramolecular kcal/mol ketones kinetic ligand substitution mechanism metal center metal-alkyl methyl migratory insertion nitrogen nucleophilic nucleophilic attack occur olefin orbital Organomet Organometallics oxidative addition palladium pathway Ph Ph Ph₂ phosphine plexes PMe3 PPh₂ PPh3 protonation react reactions reactive reagents reductive elimination regioselectivity rhodium ruthenium shown in Equation shown in Scheme solvent species stable stereochemistry steric studies substrate synthesis Tetrahedron Lett tion trans transition metal transmetallation undergo vinyl ос

About the author (2010)

JOHN F. HARTWIG, University of California, Berkeley, USA. Professor Hartwig received his B.A. degree from Princeton, USA and his Ph.D. from the University of California, Berkeley, USA. Subsequently, he was an American Cancer Society Postdoctoral Fellow at the Massachusetts Institute of Technology, USA, joined the Yale University faculty in 1992, and joined the University of Illinois chemistry faculty in July 2006. Professor Hartwig's research focuses on the discovery and mechanistic understanding of organic reactions catalyzed by organometallic complexes. He was one of the originators of palladium-catalyzed cross-coupling reactions to form carbon-heteroatom bonds, as well as palladium-catalyzed coupling of enolates and catalytic functionalization of the terminal C-H bonds in alkanes. He was recently the recipient of the 2008 Mukaiyama Award from the Society of Synthetic Organic Chemistry, Japan, the 2008 International Catalysis Award from the International Association of Catalysis Societies, the 2008 Paul N. Rylander Award of the Organic Reactions Catalysis Society, the 2007 Tetrahedron Young Investigator Award in Organic Synthesis, the 2007 Raymond and Beverly Sackler Prize in the Physical Sciences, and the 2006 ACS Award in Organometallic Chemistry.

Bibliographic information

TitleOrganotransition Metal Chemistry: From Bonding to Catalysis
AuthorJohn F. Hartwig
Editionillustrated
PublisherUniversity Science Books, 2010
Original fromthe University of California
DigitizedApr 25, 2011
ISBN189138953X, 9781891389535
Length1100 pages
Subjects ›  › 

Science / Chemistry / Organic
  
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