Graphite Intercalation Compounds and ApplicationsGraphite intercalation compounds are a new class of electronic materials that are classified as graphite-based host guest systems. They have specific structural features based on the alternating stacking of graphite and guest intercalate sheets. The electronic structures show two-dimensional metallic properties with a large variety of features including superconductivity. They are also interesting from the point of two-dimensional magnetic systems. This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds. The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and intercalated fullerenes and nanotubes. |
Contents
1 Introduction | 3 |
2 Synthesis and Intercalation Chemistry | 9 |
3 Structures and Phase Transitions | 56 |
4 Lattice Dynamics | 118 |
5 Electronic Structures | 143 |
6 Electron Transport Properties | 190 |
7 Magnetic Properties | 236 |
Other editions - View all
Graphite Intercalation Compounds and Applications Toshiaki Enoki,Masatsugu Suzuki,Morinobu Endo Limited preview - 2003 |
Graphite Intercalation Compounds and Applications Toshiaki Enoki,Masatsugu Suzuki,Morinobu Endo Limited preview - 2003 |
Common terms and phrases
Ź acceptor GICs alkali metal GICs antiferromagnetic band battery Bragg reflections Brillouin zone c-axis carbon atoms carbon fibers carbon nanotubes cell charge transfer Chem conductivity correlation length CuCl₂ GIC decreases denoted density diffraction domain donor GICs doping Dresselhaus electronic structure Endo exchange interaction FeCl3 FeCl3 GIC Fermi energy Fermi surface ferromagnetic fluorine frequency fullerenes graphene graphene sheet Graphite Intercalation Compounds graphite layers graphitic galleries Hérold hexagonal HOPG host material hydrogen in-plane structure increase intensity intercalate layers interlayer ions lattice constant liquid lithium MnCl2 modes molecules monolayer graphite neutron obtained oxide peak phase transition phonon Phys physisorption plane potassium potential pristine graphite Raman reaction resistivity samples sandwich thickness SbCl scattering shown in Figure shows Solin spectra spin stacking sequence stage number stage-1 stage-2 CoCl2 GIC substrate Suematsu superconductivity superlattice Suzuki Synth temperature dependence ternaries vector VGCF Wiesler x-ray Zabel