Amines: Synthesis, Properties and ApplicationsThe understanding of amine chemistry is of paramount importance to numerous chemical industries, as well as academic research. This book provides an authoritative account of the properties and applications of amines with respect to the characteristics of bonded substituents and the nature of their surrounding chemical and physical environments. The synthesis of alkyl, aryl and heterocyclic amines and inorganic amines with a review of their typical reactions is comprehensively treated, whilst practical synthetic and analytical methods for laboratory preparation and detection are provided. The importance of amine chemistry from the nineteenth century to the modern day, with a brief history of the development of ammonia synthesis, is included. |
Contents
I | 1 |
II | 2 |
III | 5 |
IV | 18 |
V | 25 |
VI | 33 |
VII | 55 |
VIII | 62 |
XXVII | 164 |
XXVIII | 169 |
XXIX | 171 |
XXX | 174 |
XXXI | 176 |
XXXII | 185 |
XXXIII | 188 |
XXXIV | 194 |
IX | 71 |
X | 74 |
XI | 85 |
XII | 100 |
XIII | 104 |
XIV | 109 |
XV | 116 |
XVI | 119 |
XVII | 122 |
XVIII | 123 |
XIX | 129 |
XX | 130 |
XXI | 133 |
XXII | 139 |
XXIII | 144 |
XXIV | 150 |
XXV | 157 |
XXVI | 162 |
XXXV | 202 |
XXXVI | 205 |
XL | 215 |
XLI | 216 |
XLII | 220 |
XLIII | 235 |
XLIV | 243 |
XLV | 250 |
XLVI | 263 |
XLVII | 267 |
XLVIII | 272 |
XLIX | 276 |
L | 282 |
LI | 286 |
LII | 288 |
LIII | 298 |
LIV | 303 |
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Common terms and phrases
acyl agents agrochemicals aliphatic alkyl amines alkyl groups amine oxides amino acids amino group ammonia ammonium aniline aqueous aromatic ring aryl aryl amines aziridine base benzene bond carbon catalyst CH3 CH3 Chem chemical chemistry chloramine chloride colour compounds corrosion cyclic derivatives Di-BOC diamine diazonium salts diphenylamine distillation dyes electron electrophilic ethanol ethylamine example fatty amines Figure flask Fmoc-ONSu formation H₂O halides heated heterocyclic hydrazine hydrochloric acid hydrogen hydroxide hydroxylamine imidazole kJ mol-¹ lone pair metal methyl molecular molecule nitration nitric nitro nitrogen atom nitrogen lone pair nitrogen trichloride nitrous acid nucleophilic orbitals ortho phenyl potassium presence primary amines protons pyridine pyrrole quaternary quinoline react reaction mixture reaction product Reagents Rearrangement reduced reflux resonance ring position secondary amine sodium soluble solution solvent stable structure substituted sulphuric acid synthesis synthetic temperatures tertiary amines tonnes trimethylamine yield