## Dynamics of Glassy, Crystalline and Liquid Ionic Conductors: Experiments, Theories, SimulationsThis book discusses the physics of the dynamics of ions in various ionically conducting materials, and applications including electrical energy generation and storage. The experimental techniques for measurements and characterization, molecular dynamics simulations, the theories of ion dynamics, and applications are all addressed by the authors, who are experts in their fields. The experimental techniques of measurement and characterization of dynamics of ions in glassy, crystalline, and liquid ionic conductors are introduced with the dual purpose of introducing the reader to the experimental activities of the field, and preparing the reader to understand the physical quantities derived from experiments. These experimental techniques include calorimetry, conductivity relaxation, nuclear magnetic resonance, light scattering, neutron scattering, and others. Methods of molecular dynamics simulations are introduced to teach the reader to utilize the technique for practical applications to specific problems. The results elucidate the dynamics of ions on some issues that are not accessible by experiments. The properties of ion dynamics in glassy, crystalline and liquid ionic conductors brought forth by experiments and simulations are shown to be universal, i.e. independent of physical and chemical structure of the ionic conductor as long as ion-ion interaction is the dominant factor. Moreover these universal properties of ion dynamics are shown to be isomorphic to other complex interacting systems including the large class of glass-forming materials with or without ionic conductivity.By covering the basic concepts, theories/models, experimental techniques and data, molecular dynamics simulations, and relating them together, Dynamics of Glassy, Crystalline and Liquid Ionic Conductors will be of great interest to many in basic and applied research areas from the broad and diverse communities of condensed matter physicists, chemists, materials scientists and engineers. The book also provides the fundamentals for an introduction to the field and it is written in such a way that can be used for teaching courses either at the undergraduate or graduate level in academic institutions. |

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### Contents

1 | |

9 | |

Experimental Probes for Ion Dynamics | 61 |

Electrical Response of Ionic Conductors | 89 |

NMR Experiments in Ionic Conductors | 251 |

Nanoionics | 276 |

Ionic Liquids Physics Bridging Two Fields | 311 |

Molecular Dynamics Simulations | 355 |

The Mixed Alkali Effect Examined by Molecular Dynamics Simulations | 459 |

Molecular Dynamics Simulations of Ionic Liquids | 482 |

Practical Introduction to the MD Simulations of Ionic Systems | 533 |

Some Applications and Further Problems | 551 |

Afterword | 563 |

Appendix | 569 |

593 | |

595 | |

### Other editions - View all

Dynamics of Glassy, Crystalline and Liquid Ionic Conductors: Experiments ... Junko Habasaki,Carlos Leon,K.L. Ngai No preview available - 2016 |

### Common terms and phrases

activation energy alkali ions anion Arrhenius atoms behavior caged calculated cation Chem conductivity relaxation correlation function Coupling Model crossover ð Þ dc conductivity decrease density dielectric dielectric relaxation diffusion coefficient distribution electric modulus electrode equation experimental data exponent Fourier transform fractal dimension frequency dependence glass transition glass transition temperature glass-formers grain boundary Habasaki heterogeneity Hiwatari Hove function increase ion dynamics ion hopping ionic conductors ionic liquids ionic motion K.L. Ngai Kohlrausch function Le´vy length scale Leo´n Lett low temperature materials MD simulations measured microscopic mobile ions molecular dynamics molecular dynamics simulations multifractal nanoionics Non-Cryst observed obtained oxygen parameters particles peak permittivity Phys plot potential power law primitive relaxation properties regime region sample Sect shown in Fig shows Solid State Ionics spectra stretched exponential tdif temperature dependence trajectories Þ¼ τσ