Introduction to Molecular Magnetism: From Transition Metals to LanthanidesThis first introduction to the rapidly growing field of molecular magnetism is written with Masters and PhD students in mind, while postdocs and other newcomers will also find it an extremely useful guide. Adopting a clear didactic approach, the authors cover the fundamental concepts, providing many examples and give an overview of the most important techniques and key applications. Although the focus is one lanthanide ions, thus reflecting the current research in the field, the principles and the methods equally apply to other systems. The result is an excellent textbook from both a scientific and pedagogic point of view. |
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Contents
Structure and Properties of p Magnetic Orbitals Systems | 143 |
d f | 163 |
Dynamic Properties | 179 |
SMM Past and Present | 195 |
Single Ion Magnet SIM | 217 |
SMM with Lanthanides | 239 |
Single Chain Magnets SCM and More | 251 |
Magic Dysprosium | 277 |
4 | 357 |
5 | 367 |
ESR | 375 |
3 | 378 |
4 | 391 |
5 | 404 |
8 | 417 |
2 | 41 |
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Common terms and phrases
angle anisotropy antiferromagnetic approach atoms axis behavior Benelli calculated Caneschi chain Chapter Chem chemical chemistry chiral cluster complexes compounds configuration coordination correlation corresponds crystal dependence derivatives described diamagnetic dinuclear dipolar Dy3+ effect exchange interaction excited experimental ferromagnetic g-values Gatteschi Gd3+ ground Hamiltonian hyperfine hysteresis Inorg ions iron(III Ising isotropic KGaA Kramers doublet lanthanide lanthanide ion ligands Ln3+ magnetic anisotropy magnetic field magnetic orbitals magnetic properties magnetic susceptibility measurements mechanism metal ions Mn3+ Molecular Magnetism molecules multiplet netic observed obtained organic pairs parallel paramagnetic parameters phonon Phys polyoxometalates possible presence quantum quantum tunneling qubit radical relevant reported Reproduced resonance rotation Sessoli shown in Figure single-molecule magnets spectra spintronics splitting structure symmetry Table techniques temperature tensor tion Transition Metals tunneling unpaired electrons values Wernsdorfer Wiley-VCH Verlag zero 𝜒 𝜒T