Surface and Interfacial ForcesA general introduction to surface and interfacial forces, perfectly combining theoretical concepts, experimental techniques and practical applications. In this completely updated edition all the chapters have been thoroughly revised and extended to cover new developments and approaches with around 15% new content. A large part of the book is devoted to surface forces between solid surfaces in liquid media, and while a basic knowledge of colloid and interface science is helpful, it is not essential since all important concepts are explained and the theoretical concepts can be understood with an intermediate knowledge of mathematics. A number of exercises with solutions and the end-of-chapter summaries of the most important equations, facts and phenomena serve as additional tools to strengthen the acquired knowledge and allow for self-study. The result is a readily accessible text that helps to foster an understanding of the intricacies of this highly relevant topic. |
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Contents
van der Waals Forces | 43 |
Electrostatic DoubleLayer Forces | 99 |
Capillary Forces | 131 |
Hydrodynamic Forces | 167 |
Interfacial Forces between Fluid Interfaces and across Thin | 191 |
Contact Mechanics and Adhesion | 219 |
Friction | 251 |
Solvation Forces and NonDLVO Forces in Water | 297 |
Chapter 4 | 365 |
Chapter 5 | 367 |
Chapter 6 | 370 |
Chapter 7 | 372 |
Chapter 8 | 373 |
Chapter 9 | 374 |
Chapter 10 | 375 |
Chapter 11 | 377 |
Surface Forces in Polymer Solutions and Melts | 329 |
Solutions to Exercises | 363 |
Chapter 3 | 364 |
381 | |
431 | |
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Common terms and phrases
adhesion force adsorbed approach aqueous assume atomic attractive bilayers boundary conditions bubble calculated cantilever capillary force Casimir force chain coefficient Colloid contact angle contact area curvature curves Debye Debye length decreases deformation density depends dielectric dipole dispersion DLVO theory double layer elastic electrostatic equation equilibrium example experimental Figure film thickness fluid force versus distance frequency friction force Hamaker constant hydrodynamic hydrophobic increase Instrum interaction ions leads length lipid liquid film load lubrication material measured meniscus mica microscope molecular molecules obtain optical optical tweezers osmotic particles phase Phys planar surface Poisson–Boltzmann polymer repulsion shear silicon SiO2 sliding solid surfaces solution solvent sphere spherical spring constant stick–slip superlubricity surface charge surface forces surface potential surface tension surfactant temperature theory thermal thin film typically unit area 𝑣 Vacuum van der Waals vapor pressure velocity viscosity Waals forces zero