Nickel Catalysis in Organic Synthesis: Methods and Reactions
John Wiley & Sons, Mar 9, 2020 - Science - 352 pages
A comprehensive reference to nickel chemistry for every scientist working with organometallic catalysts
Written by one of the world?s leading reseachers in the field, Nickel Catalysis in Organic Synthesis presents a comprehensive review of the high potential of modern nickel catalysis and its application in synthesis. Structured in a clear and assessible manner, the book offers a collection of various reaction types, such as cross-coupling reactions, reactions for the activation of unreactive bonds, carbon dioxide fixation, and many more.
Nickel has been recognized as one of the most interesting transition metals for homogeneous catalysis. This book offers an overview to the recently developed new ligands, new reaction conditions, and new apparatus to control the reactivity of nickel catalysts, allowing scientists to apply nickel catalysts to a variety of bond-forming reactions. A must-read for anyone working with organometallic compounds and their application in organic synthesis, this important guide:
-Reviews the numerous applications of nickel catalysis in synthesis
-Explores the use of nickel as a relatively cheap and earth-abundant metal
-Examines the versatility of nickel catalysis in reactions like cross-coupling reactions and CH activations
-Offers a resource for academics and industry professionals
Written for catalytic chemists, organic chemists, inorganic chemists, structural chemists, and chemists in industry, Nickel Catalysis in Organic Synthesis provides a much-needed overview of the most recent developments in modern nickel catalysis and its application in synthesis.
What people are saying - Write a review
We haven't found any reviews in the usual places.
Transformation of Imines via Nickelacycles
Asymmetric CC Bond Formation Reactions
Recent Advances in NiCatalyzed ChelationAssisted Direct
PhotoAssisted NickelCatalyzed CrossCoupling
Other editions - View all
activation afford alcohols aldehydes alkenes alkyl alkyl bromides alkynes allylic Angew application aryl halides asymmetric benzylic bond formation C—C bond carbon carboxylation catalytic Chem chiral chlorides cleavage CO2H Commun complex coordination coupling reactions coworkers reported cross-coupling cross-electrophile coupling derivatives developed direct electrochemical electrophiles employed enantioselective Entry equiv esters et al examples Figure followed functional give imines insertion intermediate intramolecular involving iodides isolated ketones Lett ligand mechanism mechanistic metal methods methyl Ni-catalyzed Ni(cod Ni(I Ni(II nickel nickel-catalyzed nickelalactone NiII NiIII complexes observed obtained occur Ogoshi organic organometallic oxidative addition oxidative cyclization Ph Ph presence proposed radical reaction reactivity reagents reductive reductive coupling reductive elimination resulting Scheme selectivity species stabilized step stoichiometric studies substrates synthesis tion toluene transformation undergo X-ray yield