Early Main Group Metal Catalysis: Concepts and Reactions

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Sjoerd Harder
John Wiley & Sons, Feb 18, 2020 - Technology & Engineering - 400 pages
Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.
 

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Contents

Polymerization of Alkenes and Polar Monomers by Early Main
31
4
53
Intramolecular Hydroamination of Alkenes
59
Molecular sBlock Catalysts for Alkene Hydrophosphination
93
HN and HP Bond Addition to Alkynes
123
Early Main Group MetalCatalyzed Hydrosilylation
151
Early Main Group Metal Catalyzed Hydrogenation
175
Alkali and Alkaline Earth ElementCatalyzed Hydroboration
201
Dehydrocoupling and Other Crosscouplings
225
Enantioselective Catalysis with sBlock Organometallics
251
Early Main Group Metal Lewis Acid Catalysis
279
Enantioselective Group 2 Metal Lewis Acid Catalysis
311
Miscellaneous Reactions
347
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About the author (2020)

Sjoerd Harder holds the Chair of Inorganic and Organometallic Chemistry at the University of Erlangen-Nuremberg, Germany. He has authored over 175 scientific publications, mainly on the topic of early main group metal chemistry and is considered a pioneer in heavier alkaline-earth metal chemistry and group 2 metal applications in catalysis.

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