Organosilicon Chemistry: Novel Approaches and Reactions

Front Cover
Tamejiro Hiyama, Martin Oestreich
John Wiley & Sons, Feb 18, 2020 - Science - 568 pages
Provides a unique summary of important catalytic reactions in the presence of silicon

A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals.

In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules.

-The first book about this topic in decades, covering a broad range of reactions
-Covers new approaches and novel catalyst systems that have been developed in recent years
-Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions

Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.
 

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Contents

SiH Bond Activation by MainGroup Lewis Acids
33
SiH Bond Activation by TransitionMetal Lewis Acids
87
MetalLigand Cooperative SiH Bond Activation
115
Cationic SiliconBased Lewis Acids in Catalysis
131
TransitionMetalCatalyzed CH Bond Silylation
171
TransitionMetalFree Catalytic CH Bond Silylation
213
SilylHeck SilylNegishi and Related Reactions
241
TransitionMetalCatalyzed Crosscoupling of Organosilicon
271
Lewis Base Activation of Silicon Lewis Acids
333
Hydrosilylation Catalyzed by Base Metals
417
Silylenes as Ligands in Catalysis
439
Enantioselective Synthesis of Silyl Ethers Through Catalytic SiO
459
Chiral Silicon Molecules
495
Substitution of a Carbon Substituent
507
Index
533
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About the author (2020)

Tamejiro Hiyama, PhD, is RDI Fellow at Chuo University and Professor Emeritus at Kyoto University (both in Japan). He is best known for his work in developing the Nozaki-Hiyama-Kishi reaction and the Hiyama cross-coupling. He is the recipient of the Chemical Society Award, the Humboldt Research Award, and the Frederic Stanley Kipping Award in Silicon Chemistry, and has published over 500 papers and 25 books.

Martin Oestreich, PhD, is Einstein Professor of Synthesis and Catalysis at the Technische Universitšt Berlin, Germany. His research is focused on main-group chemistry related to catalysis with emphasis on silicon and boron. He is on the editorial advisory board of European Journal of Organic Chemistry, Chemical Society Reviews, and Chemical Science, and has published over 250 papers and five books.

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