## Fundamentals of Classical Statistical Thermodynamics: Dissipation, Relaxation, and Fluctuation TheoremsBoth a comprehensive overview and a treatment at the appropriate level of detail, this textbook explains thermodynamics and generalizes the subject so it can be applied to small nano- or biosystems, arbitrarily far from or close to equilibrium. In addition, nonequilibrium free energy theorems are covered with a rigorous exposition of each one. Throughout, the authors stress the physical concepts along with the mathematical derivations. For researchers and students in physics, chemistry, materials science and molecular biology, this is a useful text for postgraduate courses in statistical mechanics, thermodynamics and molecular simulations, while equally serving as a reference for university teachers and researchers in these fields. |

### What people are saying - Write a review

We haven't found any reviews in the usual places.

### Contents

Introduction | 1 |

Introduction to TimeReversible Thermostatted Dynamical Systems | 17 |

Phase Space Expansion Calculation | 44 |

The Dissipation Theorem | 65 |

Equilibrium Relaxation Theorems | 77 |

Entropy Change for a Cyclic Temperature Variation | 104 |

### Other editions - View all

### Common terms and phrases

anti-causal antitrajectories axiom of causality Boltzmann causal Chem Clausius conjugate constant correlation function defined Definition derivation dissipation function dissipative field distribution function dynamics ensemble average equations of motion equilibrium distribution equilibrium systems equilibrium thermodynamic ergodic consistency ergodic theory ergostat ESFT Evans and Morriss Evans and Searles external field finite fluctuation relation fluctuation theorem Gibbs entropy Hamiltonian systems heat Helmholtz free energy initial distribution instantaneous dissipation internal energy irreversible isokinetic Jarzynski kinetic temperature limt Lyapunov exponents macroscopic microcanonical momenta N-particle nonequilibrium steady nonequilibrium system Nosé–Hoover thermostat ostensible phase space phase space phase space distribution phase space domain phase space expansion Phys physical phase functions physically ergodic proof quasi-static relaxation theorem reservoir reversal reversal map second law inequality shear SLLOD equations statistical mechanics steady-state strain rate system of interest T-mixing systems thermal thermodynamic temperature thermostat multiplier thermostatted particles time-averaged dissipation time-dependent transient Williams zero 𝚪 𝜏